Journal
POLYHEDRON
Volume 139, Issue -, Pages 282-288Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2017.11.002
Keywords
Halometalate; Halide complexes; Bismuth; Crystal structure; Hirshfeld surface analysis
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Funding
- Russian Science Foundation [14-23-00013]
- Russian Foundation for Basic Research [16-33-60063]
- Grant Council of President of Russia
- Russian Science Foundation [17-23-00006] Funding Source: Russian Science Foundation
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Reactions of [BiBr6](3-) and bromide salts of various substituted pyridinium cations in excess of HBr result in a series of bromobismuthate anionic complexes of various geometry and nuclearity: [{BiBr4}(n)](n-), [Bi2Br9](3-) and [Bi2Br10](4-). Hirshfeld surface analysis for 19 crystal structure was performed; impact of various X-Br contacts on the crystal structures is discussed. (C) 2017 Elsevier Ltd. All rights reserved.
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