4.6 Editorial Material

Comment on Revisiting the definition of local hardness and hardness kernel by C. A. Polanco-Ramirez, M. Franco-Perez, J. Carmona-Espindola, J. L. Gazquez and P. W. Ayers, Phys. Chem. Chem. Phys., 2017, 19, 12355

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 20, Issue 13, Pages 9006-9010

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cp04100d

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In a recent article Polanco-Ramirez et al. proposed new definitions of local chemical potential and local hardness starting from the first derivative of the energy with respect to the number of electrons and a smart use of the chain rule. In this comment we show that this derivation appears naturally in the Taylor expansion of the energy, showing that the construction of Polanco-Ramirez et al. is not artificially built.

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