Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 20, Issue 7, Pages 4739-4745Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cp08481a
Keywords
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Funding
- NSF through the Center for Ultracold Atoms
- ONR DURIP grant [N000141613141]
- MURI on Ultracold Molecules (AFOSR) [FA9550-09-1-0588]
- MURI on Quantized Chemical Reactions of Ultracold Molecules (ARO) [W911NF-12-1-0476]
- Samsung Scholarship
- NSF [1506369]
- U.S. Department of Defense (DOD) [N000141613141] Funding Source: U.S. Department of Defense (DOD)
- Division Of Physics
- Direct For Mathematical & Physical Scien [1506369] Funding Source: National Science Foundation
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We employ two-photon spectroscopy to study the vibrational states of the triplet ground state potential (a(3)Sigma(+)) of the (NaLi)-Na-23-Li-6 molecule. Pairs of Na and Li atoms in an ultracold mixture are photoassociated into an excited triplet mo(l)ecular state, which in turn is coupled to vibrational states of the triplet ground potential. Vibrational state binding energies, line strengths, and potential fitting parameters for the triplet ground a(3)Sigma(+) potential are reported. We also observe rotational splitting in the lowest vibrational state.
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