Journal
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
Volume 17, Issue 5, Pages 534-538Publisher
SPRINGERNATURE
DOI: 10.1039/c8pp00061a
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Funding
- American Chemical Society Petroleum Research Fund [58270-UR1]
- SC-INBRE grant from the National Institute of General Medical Sciences [P20 GM103499]
- Winthrop University Research Council
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A mild, redox-neutral, alkylation of imines with potassium alkyltrifluoroborates is described. The reaction proceeds under photoredox conditions at approximate to 30 degrees C with primary, secondary, and tertiary alkyltrifluoroborates, leading to alkylation products in moderate to good yield in most cases. Aryl-, vinyl-, and cyclopropyltrifluoroborates failed to react under the reported conditions.
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