Preparation of Mg(OH)2 with caustic calcined magnesia through ammonium acetate circulation

Caustic calcined magnesia (main component is MgO) can be used to produce Mg(OH)(2) by ammonium-circulation method (reaction steps: (1) MgO + 2NH(4)(+) ->(Delta) Mg2+ + 2NH(3)up arrow + H2O and (2) Mg2+ + 2NH(3) up arrow + 2H(2)O -> Mg(OH)(2) + 2NH(4)(+); Overall: MgO + H2O -> Mg(OH)2 down arrow). NH4Cl, NH4NO3 and (NH4)(2)SO4 have exhibited the ability to be used as a circulation medium. In this work, ammonium acetate (NH4Ac) was investigated as a circulation medium. The purity of the used caustic calcined magnesia (i.e., MgO content) is 85 wt.%. The results show that NH4Ac is a much more efficient circulation medium than NH4Cl, NH4NO3 or (NH4)(2)SO4 is. Step (1) in the ammonium-circulation method can be significantly accelerated if NH4Ac is used as the circulation medium. The reason for the high efficiency of NH4Ac was also analyzed. By using NH4Ac as the circulation medium, rose petal-like Mg(OH)(2) precipitate can be prepared in the presence of polyethylene glycol. The purity of the prepared Mg(OH)(2) is more than 99 wt.%. (C) 2014 Elsevier B.V. All rights reserved.