Journal
ORGANOMETALLICS
Volume 37, Issue 10, Pages 1515-1518Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00248
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Funding
- Welch Foundation [AA-1846]
- Australian Research Council [FT16010007]
- NCI and Intersect
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The reaction of 1-adamantylphosphaalkyne with 9-phenyl-9-borafluorene resulted in the insertion of the P=C unit into the endocyclic B-C bond, generating a seven-membered 1,3-boraphosphaalkene. The mechanism was investigated computationally, indicating that the reaction proceeds via a bond metathesis pathway.
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