4.5 Article

Nonradical Light-Controlled Polymerization of Styrene and Vinyl Ethers Catalyzed by an Iridium-Palladium Photocatalyst

Journal

ORGANOMETALLICS
Volume 37, Issue 3, Pages 359-366

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00783

Keywords

-

Funding

  1. JSPS KAKENHI [16H0412100]
  2. Cooperative Research Program of Network Joint Research Center for Materials and Devices
  3. JSPS from The Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [26105003]
  4. Grants-in-Aid for Scientific Research [16H04121] Funding Source: KAKEN

Ask authors/readers for more resources

A visible-light-sensitive Ir-Pd photocatalyst is effective for coordination copolymerization of styrene and vinyl ethers. The catalyst drastically accelerates styrene polymerization under visible light irradiation and allows sequence-controlled copolymerization of styrene and vinyl ethers by appropriate switching of the irradiation sequence. The reaction rates of the monomers under irradiated and nonirradiated conditions were compared. Mechanistic studies suggested that the reactions proceeded via a nonradical coordination-insertion mechanism.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available