Journal
ORGANIC LETTERS
Volume 20, Issue 14, Pages 4350-4353Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01803
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Funding
- National Natural Science Foundation of China [21602067]
- Huazhong University of Science and Technology [2016YXMS183]
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The activation of disulfides by Cu(II) salts has been realized, which triggers a highly efficient electrophilic sulfenoamination of alkenes under aerobic conditions. Various sulfenyl N-heterocycles and their Selena counterparts were produced regioselectively, with no competing disulfidation products detected. Mechanistic studies suggest a profound influence of the counterions on the Lewis acidic copper center, and the important roles of oxygen and DMSO as cooxidants for these cyclization processes.
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