Journal
ORGANIC LETTERS
Volume 20, Issue 14, Pages 4302-4305Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01734
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Funding
- NSFC [21372256, 21572264]
- State Key Laboratory of Chemical Resource Engineering
- Program for Changjiang Scholars and Innovative Research Team Project [IRT1042]
- Shandong Provincial Natural Science Foundation of China [ZR2018BB028]
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In this paper, a phosphine-catalyzed [8 + 2]-annulation of heptafulvene with allenoates has been achieved under mild conditions, giving functionalized bicyclo[5.3.0]-decane derivatives in moderate to excellent yields. Using chiral phosphine as the catalyst, optically active products were obtained in moderate to high yields with excellent enantioselectivities.
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