Journal
ORGANIC LETTERS
Volume 20, Issue 3, Pages 684-687Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03818
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Funding
- Yale University
- Sloan Foundation
- National Science Foundation (CAREER) [1653793]
- National Institutes of Health [T32GM067543]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1653793] Funding Source: National Science Foundation
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The use of allyl-palladium catalysis for the one-step alpha,beta-dehydrogenation of ketones via their zinc enolates is reported. The optimized protocol utilizes commercially available Zn(TMP)(2) as base and diethyl allyl phosphate as oxidant. Notably, this transformation operates under salt-free conditions and tolerates a diverse scope of cycloalkanones.
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