Journal
ORGANIC LETTERS
Volume 20, Issue 7, Pages 1861-1865Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00390
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Funding
- JSPS [15H03803]
- CREST, JST
- JSPS
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Trialkylphosphine organocatalysts have enabled regioselective anti-hydroboration of internal, alkynes with pinacolborane reagents to provide (E)-disubstituted alkenylboronate compounds. The alkenyl-boronate can be used for derivatizations, such as protodeborylation, Suzuld-Miyaura coupling, conjugate reduction, and Diels-Alder reactions.
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