Journal
ORGANIC LETTERS
Volume 20, Issue 13, Pages 4005-4009Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01395
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Funding
- Projects of Medical and Health Technology Development Program in Shandong Province [2015WS0102]
- Shandong Provincial Natural Science Foundation [ZR2017LB006]
- Science Foundation of Educational Commission of Shandong Province of China [J17KA248]
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A regioselective green approach for the nickel (II)-catalyzed C-N cross-coupling between arylamines and pyrazoles through a photoredox process is reported. Moderate to good yield was observed for this reaction, performed in water under air at room temperature. This strategy provides a powerful tool for the green synthesis of pyrazole-containing bioactive molecules. In addition, a single-electron-transfer mechanism is proposed in this report.
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