Journal
ORGANIC LETTERS
Volume 20, Issue 13, Pages 4116-4120Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01675
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Funding
- National Key Research and Development Program of China [2017YFC1704007]
- Ten Thousand Plan, a National High-Level Talents Special Support Plan
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Two monoterpenoid indole alkaloid erchinines A (1) and B (2), possessing unique 1,4-diazepine fused with oxazolidine architecture and three hemiaminals, were isolated from Ervatamia chinensis. Their structures were elucidated on the basis of intensive spectroscopic analysis, and a plausible biosynthetic pathway from ibogaine was proposed. Both compounds exhibited significant antimicrobial activity against Trichophyton rubrum and Bacillus subtilis, and their activities were comparable to the first line antifungal drug griseofulvin and antibiotic cefotaxime.
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