Journal
ORGANIC LETTERS
Volume 20, Issue 3, Pages 764-767Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03901
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Funding
- National Research Foundation of Korea (NRF) - Ministry of Education [2016R1D1A1B03931335]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea [20174010201160]
- National Research Foundation of Korea [2016R1D1A1B03931335] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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An efficient one-pot approach for the synthesis of diaryl sulfoxides and diaryl sulfones using aryl thiols and aryl diazonium salts was developed. The use of a visible-light-driven silver catalysis and the subsequent singlet-oxygen-induced oxidation enabled selective synthesis of sulfoxides and sulfones in the absence of a photocatalyst. The reactions were carried out under mild reaction conditions; the desired products were obtained under air atmosphere at room temperature.
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