Journal
ORGANIC LETTERS
Volume 20, Issue 10, Pages 2997-3000Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00982
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Funding
- National Natural Science Foundation of China [21572051, 21602057]
- Opening Fund of Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China)
- Hunan Normal University [KLCBTCMR201707, KLCBTCMR201708]
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A novel palladium-catalyzed tandem reaction of N-(2-iodoaryl)acrylamides with two aryl iodides for the synthesis of spirooxindole has been achieved. The reaction underwent the process of triple C-H activation and four C-C bond formations based on the double trapping of transient spirocyclic palladacycles which are obtained through remote C-H activation.
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