Journal
ORGANIC LETTERS
Volume 20, Issue 8, Pages 2168-2171Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00427
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Funding
- NIH [GM099142]
- AbbVie
- National Science Foundation [CHE 1531620, CHE 1626172]
- Division Of Chemistry [1531620] Funding Source: National Science Foundation
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM099142] Funding Source: NIH RePORTER
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The regioselective and enantioselective intermolecular sp(3) C-H functionalization of silicon-substituted alkanes was accomplished using Rh-2(S-NTTL)(4) with readily available 1-sulfonyl-1,2,3-triazoles as carbene precursors. These reactions generate a diverse array of stereodefined substituted silaalkanes.
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