Journal
ORGANIC LETTERS
Volume 20, Issue 3, Pages 776-779Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03912
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Funding
- Welch Foundation [AX-1871]
- National Institutes of Health [G12MD007591]
- National Science Foundation [CHE-1625963]
- Direct For Mathematical & Physical Scien [1625963] Funding Source: National Science Foundation
- National Institute on Minority Health and Health Disparities [G12MD007591] Funding Source: NIH RePORTER
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Dirhodium(II) catalyzed dinitrogen extrusion from diazocarbonyl compounds by 2,6-dichloropyridine-N-oxide forms ketocarbonyl compounds in near-quantitative yields. Reactions occur at room temperature, and the pyridine product does not coordinate with dirhodium(II) to inhibit catalysis. Anhydrous tricarbonyl compounds, as well as dicarbonyl compounds, are conveniently prepared by this methodology, and they have been used in situ for catalytic ene and aldol transformations.
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