Journal
ORGANIC LETTERS
Volume 20, Issue 7, Pages 2059-2062Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00603
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- State of Lower Saxony
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D-A cydopropanes bearing a simple, cydopropyl group as donor are shown to undergo a variety of [3+n]-cydaddition reactions (n = 2-4). This behavior contrasts sharply with that of common D-A cyclopropipes with aliphatic donors: Kinetic experiments demonstrate that, in terms of donor ability the cydopropyl substituent lies between electron-rich and electron-neutral aryl donors.
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