Journal
ORGANIC LETTERS
Volume 20, Issue 4, Pages 1078-1081Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b04050
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Funding
- JSPS [26248031]
- MEXT [15H05850]
- Grants-in-Aid for Scientific Research [26248031] Funding Source: KAKEN
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Alkenylation and allylation of alkyl iodides with alkenyl and allyl sulfones, respectively, took place under Pd/photoirradiation system. The initial alkyl radical, derived from a single electron transfer between Pd(0) and RI, underwent the title transformations. Pd(0) was regenerated through a reductive elimination of PhSO2PdI, which is formed by the combination of the sulfonyl radical and the palladium radical. The addition of water was effective, presumably by pushing the equilibrium through hydrolysis of PhSO2I.
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