Journal
ORGANIC LETTERS
Volume 20, Issue 9, Pages 2741-2744Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00949
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Funding
- National NSF of China [21373080, 21403062, 21273067]
- NSF of Hunan Province [2016E1007]
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A palladium-catalyzed decarbonylative alkynylation of amides via C-N bond activation is developed. Compared with the reported Ni/Cu catalyzed reaction, which only proceeded well with silylacetylenes, this transformation was also applicable to both aromatic and aliphatic terminal alkynes, including those bearing functional groups, and thus provided a general and straightforward alkynes.
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