Journal
ORGANIC LETTERS
Volume 20, Issue 12, Pages 3627-3630Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01402
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Funding
- National Natural Science Foundation of China [21622203, 21472147]
- China Postdoctoral Science Foundation [2017M613183]
- Shaanxi Provincial Key Laboratory Project [15JS004]
- Baoji University of Arts and Sciences [ZK15046, 2017dc107]
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A K2S2O8/TEMPO-induced oxidative cyclization of N-unprotected enaminoesters and enaminones that gave 1H-pyrrol-2(3H)-ones in good yields with broad functional group compatibility is reported. This method provides easy access to 1,2-carbon migration of ester or acyl group under transition-metal-free conditions.
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