Journal
ORGANIC LETTERS
Volume 20, Issue 4, Pages 1191-1194Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00114
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Funding
- Nanjing Tech University
- Natural Science Foundation of Jiangsu Province, China [BK20170965]
- US National Science Foundation [CHE-1464744]
- SICAM Fellowship by Jiangsu National Synergetic Innovation Center for Advanced Materials
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A Ni-catalyzed desymmetrizing cross-electrophile coupling of cyclic meso-anhydrides with aryl triflates has been successfully demonstrated. This is the only example using cyclic meso-anhydrides in cross-electrophile coupling reactions. A diverse array of valuable gamma-keto acid building blocks can be generated under these conditions with excellent functional group tolerance and stereochemical fidelity.
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