Journal
ORGANIC LETTERS
Volume 20, Issue 8, Pages 2160-2163Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00420
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Funding
- NSFC [21525208, 21472186]
- Henan Normal University [5101034011009, qd16111]
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Rh(III)-catalyzed cascade C-H activation of benzoylacetonitriles and annulation with sulfoxonium ylides was realized, leading to selective synthesis of naphthols, 2,3-dihydronaphtho[1,8-bc]pyrans, and naphtho[1,8-bc]pyrans. This step-economic reaction proceeded efficiently under mild and redox-neutral conditions via multiple C-H activations.
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