Journal
ORGANIC LETTERS
Volume 20, Issue 3, Pages 760-763Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03896
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Funding
- Fonds der Chemischen Industrie (Liebig-Fellowship)
- German Research Foundation (DFG)
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An efficient cross-coupling of sodium or lithium sulfinates with aryl iodides, using a combination of nickel and photoredox catalysis, is described. The dual catalyst system enables a versatile synthesis of aryl sulfones at room temperature in good yields and displays a broad functional group compatibility. The potential utility of this method in the late-stage diversification of complex molecules and in the conversion of organolithium reagents and sulfur dioxide into sulfones is demonstrated.
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