Journal
ORGANIC LETTERS
Volume 20, Issue 6, Pages 1538-1541Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00106
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Funding
- Program of High-level Talents of Inner Mongolia University [21300-5165152]
- National Science Foundation [NSF 21662025]
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A novel palladium-catalyzed domino cyclization/alkylation of terminal alkynes was achieved for the synthesis of alkynyl-functionalized 3,3-disubstituted azaindoline derivatives under air atmosphere conditions. Various types of terminal alkynes, including aromatic alkynes, aliphatic alkynes, and ferrocene acetylene, can undergo the process successfully. The protocol provides a range of alkynyl-functionalized azaindoline scaffolds bearing a quarternary carbon center.
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