Journal
ORGANIC LETTERS
Volume 20, Issue 7, Pages 1995-1998Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00545
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Funding
- MOST [2015CB856600]
- NSFC [21332001, 21431008]
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The first successful catalytic borylation of unactivated aromatic C-N bonds of tertiary anilines without the preactivation or any directing groups is demonstrated. The reactivity of both N,N-dialkylarylamines and N-arylpyrroles were investigated systematically, and the targeted products were furnished in moderate to good yields. The DFT calculation results indicated that the catalytic cycle is furnished via a five-membered cyclic transition-state due to the steric hindrance of the Ni/NHC catalytic system.
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