Journal
ORGANIC LETTERS
Volume 20, Issue 7, Pages 1953-1956Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00496
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Funding
- Japan Society for the Promotion of Science KAKENHI [25410110, 16K05768]
- Grants-in-Aid for Scientific Research [16K05768, 25410110] Funding Source: KAKEN
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Vinylsilanes were directly prepared from the corresponding vinyl triflates under magnesium-promoted reductive conditions in THF with no transition metal catalyst, and gem-bis-silylated compounds were obtained in NMP. Investigation of the redox potential of starting materials and products suggested that reductive coupling reactions of vinyl triflates might be controlled by the reduction potential. A variety of gem-bis-silylated compounds and 3-silyladipic acid esters were easily synthesized in only two steps from vinyl triflates in high yields.
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