Journal
ORGANIC LETTERS
Volume 20, Issue 11, Pages 3381-3384Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01305
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Funding
- SERB under the Green Chemistry Programme [EMR/2015/30]
- CSIR-INPROTICS Pharma Agro [HCP0011A]
- UGC
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A simple and efficient Mn-catalyzed acylation of amines is achieved using both acyl and alkoxy functions of unactivated esters with the liberation of molecular hydrogen as a sole byproduct. The present protocol provides an atom economical and sustainable route for the synthesis of amides from esters by employing an earth-abundant manganese salt and inexpensive phosphine-free tridentate ligand.
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