Journal
ORGANIC LETTERS
Volume 20, Issue 11, Pages 3362-3366Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01281
Keywords
-
Categories
Funding
- Indian Institute of Technology Madras [CHY/16-17/840/RFIR/ANBA]
- CSIR, New Delhi
Ask authors/readers for more resources
An efficient and chemodivergent palladium-catalyzed thiolation (C-S) and imidation (C-N) of directing group assisted C-H bonds have been accomplished employing N-(arylthio)imides in combination with either Bronsted acid or Lewis acid, respectively. Notable features of the developed methodologies include excellent diversity, high functional group tolerance, wide substrate scope, and use of a single N-S reagent. Importantly, the developed hypothesis was also successfully extended to the amidation of C-H bonds. A plausible mechanistic pathway was proposed based on the preliminary mechanistic study.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available