4.8 Article

Total Synthesis of the Neoclerodane Diterpene Salvinorin A via an Intramolecular Diels-Alder Strategy

Journal

ORGANIC LETTERS
Volume 20, Issue 11, Pages 3418-3421

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01357

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Funding

  1. Deutsche Forschungsgemeinschaft [ME 776/20-2]

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A concise total synthesis of the neoclerodane diterpene salvinorin A from 3-furaldehyde is reported using two highly diastereoselective intramolecular Diels-Alder reactions (IMDA) as the key transformations.

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