Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 16, Pages 2865-2869Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00630j
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- Department of Science and Technology (DST), New Delhi [SB/S1/OC-17/2013]
- CSIR
- UGC
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Gold(I)-catalyzed cross-coupling reactions of aryldiazonium salts with organostannanes are described. This redox neutral strategy offers an efficient approach to diverse biaryls, vinyl arenes and arylacetylenes. Monitoring the reaction with NMR and ESI-MS provided strong evidence for the in situ formation of Ph3PAuIR (R = aryl, vinyl and alkynyl) species which is crucial for the activation of aryldiazonium salts.
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