Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 3, Pages 490-498Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02892j
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A cascade radical cyclization/sulfenylation or selenylation of beta,gamma-unsaturated hydrazones and oximes was realized under mild conditions with phenyliodine(III) diacetate (PIDA) as the sole oxidant, leading to the construction of diversely functionalized heteroatom-containing pyrazoline and isoxazoline derivatives. This metal-free radical process is suggested to encompass a sequential C-N/O and C-S/Se bond fomation.
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