Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 25, Pages 4715-4719Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob01063c
Keywords
-
Categories
Funding
- University of Connecticut Office of Undergraduate Research
- Presidential Scholars Enrichment Award Fund
Ask authors/readers for more resources
We present an alcohol oxidation strategy to access -trifluoromethyl ketones (TFMKs) merging catalytic oxoammonium cation oxidation with visible-light photoredox catalysis. This work uses 4-acetamido-(2,2,6,6-tetramethyl-piperidin-1-yl)oxyl as an organic oxidant capable of generating TFMKs in good yields. The methodology serves as an improvement over previous reports of an analogous oxidation strategy requiring superstoichiometric quantities of oxidant. Both primary and secondary non-fluorinated alcohols can also be oxidised in good yields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available