Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 2, Pages 295-301Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02624b
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- University of Torino
- Ministero dell'Universita e della Ricerca
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Diazonium salts, and precisely arenediazonium o-benzenedisulfonimides, have been used for the first time as efficient electrophilic partners in gold catalyzed Heck-coupling reactions. The synthetic protocol was general, easy and gave the target products in satisfactory yields. Mechanistic insights revealed the fundamental roles of the o-benzenedisulfonimide anion as an electron transfer agent thath promotes a radical pathway that does not require the presence of photocatalysts or external oxidants.
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