Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 27, Pages 4977-4984Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00755a
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Funding
- National Key R&D Program of China [2017YFA0207201]
- Natural Science Foundation of China [21501085]
- Natural Science Foundation of Shandong Province [ZR2017MB052, ZR2017MB060]
- Key University Science Research Project of Jiangsu Province [17KJA150004]
- Liaocheng University Funds for Young Scientists [31805]
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A new family of aggregation-induced emission (AIE)-active monoboron and bisboron complexes based on benzothiazole-hydrazone chelates was synthesized. These complexes showed very weak fluorescence in fluid solution due to active intramolecular rotation and were emissive in high-viscosity solvents or in the aggregation state. Single crystal X-ray diffraction analyses and theoretical calculations were carried out to explain AIE behavior. The large Stokes shifts (3590-7400 cm(-1)) and relatively highly efficient solid-state emission make these complexes valuable AIE luminophores for further potential applications.
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