4.6 Article

Stereocontrolled glycoside synthesis by activation of glycosyl sulfone donors with scandium(III) triflate

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 2, Pages 325-335

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02792c

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Funding

  1. CNRS
  2. CHARM3AT Labex program [ANR-11-LABX-39]
  3. Labex Saclay Plant Sciences-SPS [ANR-10-LABX-0040-SPS]

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The activation of aryl glycosyl sulfone donors has been achieved using scandium(III) triflate and has led to the selective preparation of alpha-mannosides resulting from a post-glycosylation anomerization.

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