Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 17, Pages 3099-3103Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob00488a
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Funding
- Natural Science Foundation of Jiangxi Province [20161BAB203084]
- NSFC [21762025, 21702027, 21562026]
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An efficient palladium-catalyzed carbonylation reaction of readily available quaternary ammonium salts with CO is reported for the first time to afford arylacetamides and arylacetic acid esters via benzylic C-N bond cleavage. This protocol features mild reaction conditions under atmospheric pressure of CO, a redox-neutral process without an additional oxidant, and a broad substrate scope for various kinds of amines, alcohols and phenols.
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