Journal
NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 13, Pages 11131-11136Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj02226g
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Funding
- NPRP award from the Qatar National Research Fund (member of Qatar Foundation) [8-094-1-018]
- National University of Singapore [143-000-656-597]
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Oxidative cleavage of aromatic alkenes and oxidation of alkynes have been catalyzed by a simple Fe(II) complex [Fe(CH3CN)(6)][BF4](2) using H2O2 as an oxidant at room temperature. A free radical mechanism has been proposed involving the peroxy (OOH) radical to account for our experimental findings.
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