4.6 Article

New porphyrin-based dendrimers with alkene linked fluorenyl antennae for optics

Journal

NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 1, Pages 395-401

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj03522e

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Funding

  1. China Scholarship Council (CSC)
  2. Ministere de l'Enseignement Superieur et de la Recherche Scientifique de Tunisie
  3. departmental committees CD35 and CD85 of the Ligue contre le Cancer du Grand-Ouest

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The design of porphyrin-based dendrimers featuring conjugated dendrons via alkene spacers herein demonstrates their important role in determining linear optical properties, as well as two-photon absorption (PA) and singlet oxygen photosensitising properties. Improvement in these properties compared to those observed for their analogous alkyne spacers makes these molecules appealing for combined 2-photon-based photodynamic therapy (PDT) and imaging.

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