Journal
NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 1, Pages 25-28Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj02820b
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- Australian Research Council [DE130100615]
- University of Melbourne
- Australian Research Council [DE130100615] Funding Source: Australian Research Council
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The microwave-assisted reaction of (TBA)(4)[beta-Mo8O24] and (TBA)(3)[H3V10O28] with pentaerythritol or tris(hydroxymethyl)amino-methane yields polyanions with the general formula (TBA)(2)[V3Mo3O16-(O-3-R)] (R: C5H8OH - 1; R: C4H6NH2 - 3). Post-synthetic esterification of 1 yields the acylated derivative 2, with all compounds being characterized in the solid and solution state.
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