4.6 Article

Highly selective and sensitive chemosensor based on 2,3-diaminophenazine hydrochloride for the detection of cyanide in pure water and its application in plant seed samples

Journal

NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 18, Pages 14766-14771

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj02316f

Keywords

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Funding

  1. National Natural Science Foundation of China [21662031, 21661028, 21574104]
  2. Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China [IRT 15R56]

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In this study, we prepared an efficient chemosensor based on 2,3-diaminophenazine hydrochloride, and it exhibited good dissolvability in water; more importantly, it could act as an efficient chemodosimeter for the selective detection of CN- in pure water. Upon reacting with CN-, 2,3-diaminophenazine hydrochloride (Q1) displayed a remarkable visible and fluorescence response simultaneously with significant changes in both absorption and fluorescence spectra. Furthermore, the absorption and fluorescence detection limits of CN- were 1.95 x 10(-7) M and 1.13 x 10(-9) M, respectively. For practical applications, test strips based on this chemosensor could serve as convenient CN- detection tools. The chemosensor was also successfully applied to the detection of CN- in plant seeds and several natural water samples.

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