Journal
NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 10, Pages 8220-8229Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj00300a
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Funding
- Robert A. Welch Foundation [E-680]
- CNRS [UMR UB-CNRS 6302]
- Universite de Bourgogne Franche-Comte
- FEDER-FSE Bourgogne (European Regional Development Fund)
- Conseil Regional de Bourgogne'' through the PARI II CDEA project
- Conseil Regional de Bourgogne'' through JCE program
- ANR
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Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five-and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.
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