Journal
NEW JOURNAL OF CHEMISTRY
Volume 42, Issue 14, Pages 11972-11978Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nj02012d
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [51573074]
- Fundamental Research Funds for the Central Universities [JUSRP51624A]
- Excellent Youth Natural Science Foundation of Jiangsu Province [BK20170053]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX17_1429]
Ask authors/readers for more resources
Fine dispersion of nanocrystalline cellulose (NCC) in a bacterially synthesized poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) matrix is challenging due to their incompatibility. To improve their compatibility, NCC was first grafted with PHBH, marked as NCC-g-PHBH, using (3-aminopropyl)triethoxysilane (APES) as a coupling agent, leading to a grafting degree of approximate to 25 wt%. The grafting mechanism and the mechanical and crystallization behaviors of the PHBH/NCC-g-PHBH blends, prepared via solution casting, were systematically investigated. The NCC was uniformly dispersed in the PHBH matrix after grafting with PHBH. As a consequence, the mechanical and crystallization properties of the PHBH were greatly improved in the presence of the NCC-g-PHBH. With the addition of 1.0 wt% NCC-g-PHBH, the Young's modulus of the PHBH/NCC-g-PHBH blend was increased by 15%, which is further evaluated by the Halpin-Tsai model, while the surface contact angles decreased by 30 degrees. Furthermore, the presence of NCC-g-PHBH copolymers greatly increased the nuclei density and decreased the spherulite size of PHBH without changing the crystal structures. Therefore, this work provided a novel route to prepare fully biodegradable and bio-based PHBH nanocomposites, which may broaden the application range of PHBH.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available