Journal
NATURAL PRODUCT REPORTS
Volume 35, Issue 6, Pages 559-574Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7np00069c
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Funding
- NIH-NIGMS [R01GM080269]
- Amgen
- Gordon and Betty Moore Foundation
- Caltech
- NSF [DGE-1144469]
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM080269] Funding Source: NIH RePORTER
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Enantioselective Pd-catalyzed allylic alkylations of prochiral enolates represent a powerful tool for the construction of all-carbon quaternary stereocenters. This review describes the emergence of such reactions as strategic linchpins that enable efficient, stereocontrolled syntheses of Aspidosperma and related monoterpene indole alkaloids.
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