4.8 Article

Covalent functionalization of black phosphorus nanoflakes by carbon free radicals for durable air and water stability

Journal

NANOSCALE
Volume 10, Issue 13, Pages 5834-5839

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr06085h

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Funding

  1. National Science Foundation of China [21707059]
  2. Natural Science Foundation of Gansu [17JR5RA213]
  3. Fundamental Research Funds for the Central Universities [lzujbky-2016-k08]
  4. Key Laboratory of Catalytic Engineering of Gansu Province
  5. Key Laboratory of Resources Utilization, Gansu Province

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This work developed a simple and efficient method to covalently functionalize black phosphorus nanoflakes (BPNFs) with carbon free radicals from azodiisobutyronitrile (AIBN) molecules. BPNFs after successful modification (BPNFs-AIBN) not only had good stability in air and aqueous solution, but also still maintained good optical properties.

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