Journal
NANOSCALE
Volume 10, Issue 32, Pages 15222-15228Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8nr02833h
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Funding
- National Basic Research Programs of China (973 Program) [2014CB931800, 2011CB935700]
- Chinese National Science Foundation [21571010, U0734002]
- Chinese Aeronautic Project [2013ZF51069]
- 111 Project [B14009]
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Currently, MoS2 is being investigated as a lithium-ion battery (LIB) anode material because of its high theoretical capacity. However, its significantly low electrochemical activity and cyclic stability limit its utilization. Nevertheless, small-sized MoS2 possibly overcomes these issues. Herein, small-sized MoS2 with uniform particle sizes of about 20-30 nm was prepared via a novel solution-based microwave-assisted precursor pyrolysis method. The resultant MW-MoS2 sample has a high surface area of 96.9 m(2) g(-1) and large pore volume (0.38 cm(3) g(-1)) with pore size distribution mainly in the meso/macropore scale, which are beneficial for electrolyte storage and low charge carrier conductive resistances. The large pore surface area and volume of the small-sized MoS2 can also ease the volume expansion during the charging and discharging process. As an LIB anode, the MW-MoS2 material exhibits an amazingly large specific capacity of 1355 mA h g(-1) at a low current density of 0.5 A g(-1). At a high current density of 10 A g(-1), a specific capacity of 435 mA h g(-1) is obtained, demonstrating its excellent rate capability. Furthermore, a large discharge capacity of 544 mA h g(-1) is maintained after 500 cycles at 5 A g(-1), indicating its fascinatingly high cyclic stability.
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