4.8 Article

Graphene-Based Adaptive Thermal Camouflage

Journal

NANO LETTERS
Volume 18, Issue 7, Pages 4541-4548

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.8b01746

Keywords

Graphene optoelectronics; variable emissivity; electrolyte gating; thermal camouflage; thermal emission; multilayer graphene; reconfigurable surface; heat management; IR optics

Funding

  1. European Research Counsel [682723]
  2. BAGEP Award of the Science Academy
  3. EPSRC [EP/K005014/1] Funding Source: UKRI

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In nature, adaptive coloration has been effectively utilized for concealment and signaling. Various biological mechanisms have evolved to tune the reflectivity for visible and ultraviolet light. These examples inspire many artificial systems for mimicking adaptive coloration to match the visual appearance to their surroundings. Thermal camouflage, however, has been an outstanding challenge which requires an ability to control the emitted thermal radiation from the surface. Here we report a new class of active thermal surfaces capable of efficient real-time electrical control of thermal emission over the full infrared (IR) spectrum without changing the temperature of the surface. Our approach relies on electro-modulation of IR absorptivity and emissivity of multilayer graphene via reversible intercalation of nonvolatile ionic liquids. The demonstrated devices are light (30 g/m(2)), thin (<50 mu m), and ultraflexible, which can conformably coat their environment. In addition, by combining active thermal surfaces with a feedback mechanism, we demonstrate realization of an adaptive thermal camouflage system which can reconfigure its thermal appearance and blend itself with the varying thermal background in a few seconds. Furthermore, we show that these devices can disguise hot objects as cold and cold ones as hot in a thermal imaging system. We anticipate that, the electrical control of thermal radiation would impact on a variety of new technologies ranging from adaptive IR optics to heat management for outer space applications.

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