Journal
MOLECULES
Volume 23, Issue 6, Pages -Publisher
MDPI
DOI: 10.3390/molecules23061347
Keywords
insect sex pheromone; tea tussock moth; total synthesis; resource chemistry
Funding
- National Natural Science Foundation of China [31301712, 21502151]
- Opening Funds of Key Laboratory of Synthetic Chemistry of Natural Substances
- Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
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Synthesis of the sex pheromone of the tea tussock moth in 33% overall yield over 10 steps was achieved. Moreover, the chiral pool concept was applied in the asymmetric synthesis. The synthesis used a chemical available on a large-scale from recycling of wastewater from the steroid industry. The carbon skeleton was constructed using the C4+C5+C8 strategy. Based on this strategy, the original chiral center was totally retained.
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