Journal
MICROCHIMICA ACTA
Volume 185, Issue 2, Pages -Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-017-2624-2
Keywords
Electrochemical sensor; Transmission electron microscopy; Cyclic voltammograms; Dealloying; Differential pulse voltammetry
Categories
Funding
- National Natural Science Foundation of China [51371004]
- Major Natural Science Foundation of Jiangsu Provincial Education Department [16KJA150007, 13KJA430001]
- Qing Lan Project [SZ2014005]
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A nanoporous platinum-yttrium alloy (NP-PtY) was fabricated by dealloying ribbons of a PtYAl alloy. Owing to the high porosity and the synergistic effect of Y in the Pt backbone, the NP-PtY exhibits superior structural stability, reproducibility and electrocatalytic activity. An electrochemical sensor was developed for the highly sensitive and selective detection of dopamine (DA) based on the use of a glassy carbon electrode modified with NP-PtY alloy and graphene. The sensor, best operated at 0.16 V vs. SCE, has a linear range covering the 0.9 to 82 mu M concentration range, a 0.36 mu M detection limit (at S/N = 3), and good selectivity over tyramine, tryptamine, phenethylamine, uric acid, and ascorbic acid. It gave satisfactory results in the determination of DA in spiked samples of urine.
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