Journal
MICROCHIMICA ACTA
Volume 185, Issue 7, Pages -Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-018-2862-y
Keywords
Calcined layered double hydroxide; Gold nanospheres; Microextraction by packed sorbent; High performance liquid chromatography; Organic filter head
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Funding
- National Natural Science Foundation of China [21405057, 21207047]
- Science and Technology Developing Foundation of Jilin Province of China [201701011106JC, 20160623025TC, 20160204010GX]
- Open Funds of the State Key Laboratory of Electroanalytical Chemistry [SKLEAC201704]
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This work describes a nanohybrid material consisting of gold nanoparticles (AuNPs) and nanosheets of layered double hydroxides (NLDHs) of Mg(II) and Al(III). Mono-disperse AuNPs were immobilized on the surface of the LDHs via Au-O bonding. The nanohybrid sorbent was packed in an organic filter along with a syringe and applied to the microextraction of triazine herbicides with the help of an injection pump. The collected hexane eluate was concentrated and directly injected into a HPLC column for quantification. The effects of the amount of Au/LDH nanohydrobrids, type, flow rate, volume of washing and eluting solvent were optimized. The method was validated by detecting four triazine herbicides (prometryn, atrazine, terbumeton and secbumeton) in spiked maize. The limits of detection range between 35 and 108 pg g(-1). The relative standard deviations range from 1.0-6.9% for repeatability and 4.6-7.8% for reproducibility (for n = 5).
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